You can remove an alias address from a distribution group in Office 365 using PowerShell with the Set-DistributionGroup cmdlet. If you need to add an alias, see this post.
Here is an example to remove a single alias from a distribution group with PowerShell:
Set-DistributionGroup "TestGroup" -EmailAddresses @{remove="EmailToRemove@tachytelic.net"}
Fill the form below and copy the generated the PowerShell code:
You will be prompted for your Office 365 credentials and your session will be established and the email address will be removed from the distribution group.
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